Spotlighting the Environmental Science and Chemistry Department
This summer in the Queens lab, students are joining Dr. Aaron Socha, a natural product chemist teaching in the Environmental Science and Chemistry Department, in pursuit of sustainable energy. Queens students Gabbi Montgomery, Albratha McClain, Hannah Phykitt, Michael Gonzalez, alumni Victoria Diaz, high schoolers Andrew DeWeese, Sam Quarles and Charlie Veronee, and postdoctoral researcher Shihong Liu are facing a complex problem.

With industry puffing on a finite supply of petroleum and coughing up carbon dioxide emissions, it is time to look for an alternative. “We [use] oil to drive our cars, rubber to make tires . . . even fine chemicals and pharmaceuticals are often derived from petroleum,” said Socha. “Solvents, plastics, paints: small things add up.” Where everything seems to trace back to fossil fuels, scientists like Socha see plants as one future source of renewable materials.
Since they are “reproducible, sustainable, and produce oxygen,” Socha believes that plants are a suitable replacement for some of our chemical dependencies. Unfortunately, this switch will take a lot more than a green thumb. Socha explained that a “chemical conversion process” is required. “Plants are largely made of carbon-based polymers. . . We have to figure out how to convert plant carbon into a usable form.”
Backed by the U.S. Department of Energy and the National Science Foundation, and collaborating with the Lawrence Berkeley National Laboratory and Natural Fiber Welding, Queens is in good company. In Rogers Hall, a state of the art science building on campus, the Domtar pulp and paper corporation also leases space to work on biomaterials projects with Queens student interns and graduates.
A number of scientists across the world are working to replace petroleum in industrial products, and Queens has its own strategy. “We have very specific materials that we are making at Queens” explained Socha. “These materials are largely known as ionic liquids.”
Ionic liquids are a “unique group of chemicals – they are composed of pure ions, yet are often liquids at room temperature” says Socha. Due to their “tunable” solvent properties, ionic liquids can dissolve a wide range of substrates, and because they are ionic, they remain in liquid form at temperatures that would boil other liquids. These properties can be attractive to industries using large volumes of chemical solvents for materials processing – on the one hand, you can optimize solubilities of target molecules, and on the other hand your evaporative loss and environmental impact is minimized.
To start, Socha’s team had to find the ideal plant material to work with. “In the early stages of this work we looked to a very abundant and inexpensive feedstock,” said Socha. They
selected lignin “essentially, a waste product from the pulp and paper industry that is also known as ‘black liquor’. In a pulp mill, lignin is typically burned for heat, “but it’s pretty well-oxidized already, so it has a low value as a fuel” said Socha.
Essentially, lignin is what Socha calls a “large volume waste product” and it is also very local. “At least sixty tons of lignin per day are generated here in North Carolina,” said Socha. The team at Queens is working to convert lignin excess into “benzylammonium ionic liquids that can perform comparably to petroleum-based ionic liquids in certain applications.”
This conversion process involves breaking down the lignin into smaller fragments using elevated pressures and temperatures. “This is of particular interest to the students in the lab at Queens because they learn to use powerful reactors, and cutting-edge analytical instruments to measure their product yields.” One end-goal for the lignin-derived ionic liquids are their use as solvents for biopolymers . Known as biomass pretreatment, this application spans biotech industries (think fuels and pharmaceuticals) as well as emerging industries focused on sustainable textile manufacturing.
As this process evolves, there are other elements to take into consideration. “If these ionic liquids are considered for use at a large scale we will need to evaluate their environmental toxicity,” said Socha. Plugged into the rich scientific network at Queens, interdisciplinary experiments are being developed. Socha’s team is “working with the department of Biology . . . to have students test the toxicity their ionic liquids – specifically those made from different types of plants’ lignin,” said Socha. Dr. Scott Weir, a professor in the department of Biology, is leading students in research design to determine if grass-derived liquids are less toxic than wood-derived liquids, for example.
Socha, and bright new minds in diverse fields of science, are tackling a challenging project in the labs at Queens. They are determined to create new biomaterials from plants in a cost-effective way. Socha cites “54 existing commercial applications of ionic liquids” and a desperate need for petroleum alternatives. The College of Arts and Sciences is excited to be sprouting green solutions at Queens.























